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Borik Asit Üretiminde Amonyum Tuzları, İnorganik ve Organik Asit Liç Sistemlerinin İncelenmesi - Investigation of Ammonium Salts, Inorganic and Organic Acid Leaching Systems in Boric Acid Production
2009
Journal:  
Bilimsel Madencilik Dergisi
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Abstract:

  Türkiye yaklaşık 800 milyon ton rezervi ile dünyanın en büyük bor kaynaklarına sahiptir. Kolemanit, üleksit ve tinkal Türkiye‘de en fazla çıkartılan bor mineralleridir. Bu mineraller rafine boraks, perborat, boraks dekahidrat ve borik asit gibi çeşitli bor bileşiklerinin üretiminde hammadde olarak kullanılırlar. Bu bor bileşikleri özellikle cam, seramik ve deterjan sanayileri gibi farklı endüstrilerde kullanılmaktadır. En önemli bor bileşiklerinden biri olan borik asit, hidrometalürjik bir yöntemlerle, genellikle kolemanit cevher ve konsantrelerinin yüksek sıcaklıklarda sülfürik asitle liçi ve yüklü/doygun liç çözeltilerinden borik asitin kristallendirilmesi ile elde edilmektedir. Ancak, özellikle son yıllarda, sülfürik asite alternatif olarak diğer inorganik asitler, organik asitler ve amonyum tuzları borik asit üretimi için geniş bir şekilde araştırılmıştır. Borik asit, bu reaktiflerle bor minerallerinin hidrometalurjik reaksiyonu sonucu elde edilmektedir. Bu makalede, bor bileşiklerinin endüstrideki kullanım alanları, borik asit üretimi, potansiyel reaktif sitemleri ve kimyasal esasları incelenmiştir.  Anahtar Sözcükler: Borik asit, Liç, Asit, Amonyum tuzu  ABSTRACT  Turkey has the largest boron resources in the world with an estimated ore reserve of approximately 800 million tonnes. Colemanite, ulexite and tincal are the most important boron minerals that are mined in Turkey. These minerals are used as the raw materials in the production of various boron compounds such as refined borax, perborate, borax decahydrate and boric acid for use in different industries including glass, ceramic and detergent industries. One of the most significant boron compounds, the boric acid is produced by hydrometallurgical processes, which generally involve the sulphuric leaching of colemanite ores/concentrates at high temperatures followed by the crystallization of boric acid from loaded/saturated solutions at low temperatures. However, in recent years, potential reagent systems (other inorganic acids, organic acids and ammonium salts) have been extensively investigated as an alternative to sulphuric acid treatment for the extraction of boric acid. In this paper, the industrial use of boron compounds, production of boric acid, potential reagent systems and their chemical fundamentals were critically reviewed.  Keywords: Boric acid, Leaching, Acid, Ammonium salt 

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Bilimsel Madencilik Dergisi

Field :   Mühendislik

Journal Type :   Uluslararası

Metrics
Article : 118
Cite : 61
2023 Impact : 0.083
Bilimsel Madencilik Dergisi