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SYNTHESIS AND CRYSTAL STRUCTURE OF HG(II) COORDINATION POLYMER WITH THE RIGID 4,4'-ABPY
2017
Journal:  
The Online Journal of Science and Technology
Author:  
Abstract:

The new coordination polymer with saccharinate (sac) and 4,4'-azobispyridine (azpy), namely [Hg(sac)2(μ-azpy)2]n was synthesized and single crystal X-ray diffraction. Single crystal Xray analysis reveals that sac ligand acts N-coordinated and 4,4'-abpy ligand exhibits as bridging ligand. In complex, the Hg(II) ion and all ligands are linked by coordination bonds and 4,4'-abpy ligands connect the Hg(II) centers forming a one-dimensional coordination polymer. In complex, the sac ligands N-coordinated to the Hg(II) ion and distorted tetrahedron geometry of Hg(II) ion is completed by bridging 4,4'-abpy ligands.

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The Online Journal of Science and Technology

Journal Type :   Uluslararası

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Article : 334
Cite : 68
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The Online Journal of Science and Technology