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Synthesis, spectroscopic characterization, crystal structure and DNA docking studies of a new trans-platinum saccharinate complex containing aqua and dimethyl sulfoxide ligands
2024
Journal:  
Journal of the Turkish Chemical Society Section A: Chemistry
Author:  
Abstract:

A new trans-platinum complex, trans-[Pt(sac)2(H2O)(DMSO)] (sac= saccharinate; DMSO= dimethyl sulfoxide), was synthesized and characterized by elemental analysis, UV, FTIR, NMR spectroscopy and X-ray single-crystal diffraction. In the mononuclear complex, the platinum(II) cation was coordinated by two N-coordinated sac ligands in the trans position, the sulfur atom of the DMSO ligand, and an aqua ligand, forming a distorted square planar coordination geometry. The interaction of the platinum(II) complex with DNA was studied using molecular docking. The complex successively docked into the minor groove of DNA via intermolecular hydrogen bonds with the adenine, cytosine, and guanine bases.

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2024
Author:  
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Journal of the Turkish Chemical Society Section A: Chemistry

Field :   Fen Bilimleri ve Matematik

Journal Type :   Ulusal

Metrics
Article : 843
Cite : 325
2023 Impact : 0.03
Quarter
Basic Field of Science and Mathematics
Q4
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Journal of the Turkish Chemical Society Section A: Chemistry