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Yeşil kimya ile iletken polimer sentezi ve elektrokromik özellikleri
2017
Journal:  
Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi
Author:  
Abstract:

İletken polimerler ilginç optik ve elektriksel özellikleri sayesinde teknolojik uygulamalarda kullanım potansiyeli en yüksek malzemelerden biridir. Fakat iletken polimerlerin zayıf çözünürlüğü, kolayca işlenememesi, mekanik dayanımının ve stabilitesinin iyi olmaması gibi nedenler pratik uygulamalarda kullanımını sınırlandırmaktadır. Bu çalışmada iletken polimerler organik çözücüler (diklorometan, asetonitril, kloroform vb.) yerine polistirensülfonikasit yardımıyla hazırlanan sulu dispersiyonunun elektrokimyasal olarak polimerleştirilmesiyle elde edilmiştir. Böylelikle suda çözünmeyen bir monomer, çevre ve insan sağlığına zararlı organik çözücüler yerine sulu ortamda polimerleştirilmiştir. Ayrıca sulu ortamda elde edilen iletken polimerin organik çözücü varlığında elde edilen iletken polimere göre optik ve elektriksel özelliklerinin daha üstün olduğu saptanmıştır. Bu makale ile çevre ve insan sağlığına zararlı organik çözücülerde sentezlenen diğer iletken polimerlerin de sulu ortamda sentezlenebileceği ve elde edilen polimerlerin teknolojik uygulamalarda kullanımı için çok önemli olan optik ve elektriksel özelliklerinin daha üstün olabileceği gösterilmiştir.

Keywords:

Conductive polymer synthesis and electrochromatic properties with green chemistry
2017
Author:  
Abstract:

Conductive polymers are one of the highest materials with potential for use in technological applications thanks to their interesting optical and electrical characteristics. But reasons such as the weak resolution of conductive polymers, their failure to process, their mechanical resistance and stability are not good limit their use in practical applications. In this study, the conductive polymers are organic solvents (dychloromethan, acetonitril, chlorform, etc.) It is obtained by electrochemical polymerization of the water dispersion prepared with the help of polistirensulfonikasite. Thus, a monomer that is not water-soluble is polymerized in a water environment instead of organic solvents that are harmful to the environment and human health. It is also found that the conductive polymers obtained in the water environment are superior to the conductive polymers obtained in the presence of organic solvent. This article has shown that other conductive polymers synthesized in organic solvents that are harmful to the environment and human health can also be synthesized in a water environment and that the obtained polymers may be superior to their optical and electrical properties, which are very important for use in technological applications.

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Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi

Field :   Mühendislik

Journal Type :   Ulusal

Metrics
Article : 1.968
Cite : 4.405
2023 Impact : 0.145
Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi