Abstract:

In this study, 2-(4-metoxifenylamino)2-oxetylmethrylate (MPAEMA) monomers were synthesized from sodiummethrylate with 2-chlor-N-(4-metoxifenyl)acetamide. The structure of the monomer was characterized by the FT-IR, 1H-NMR and 13C-NMR spectroscopic techniques. The MPAEMA monomerine homopolymers and methyl metacrylate (MMA) copolymers were prepared by the method of free-radical polimerization. Poli(MPAEMA) homopolymers and Poli(MPAEMA-ko-MMA) copolymers; FT-IR, 1H-NMR and 13C-NMR spectroscopic techniques, TGA/DTA thermal analysis methods and homoolimer gel passivity chromatography (GPC) were characterized. The MPAEMA monomerine MMA and the copolymers in different proportions were created by synthesizing the same method with 15% conversion. Low-reversed copolimer compounds were determined according to the Elemental Analysis results and characterization was made with FT-IR and TGA thermal analysis. The monomer reactivity rates for copolimer systems were calculated by the linear methods of Fineman Ross (FR), Kelen Tüdos (KT) and the nonlinear method of RREVM and all the results were discussed.

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