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Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones
2019
Journal:  
Düzce Üniversitesi Bilim ve Teknoloji Dergisi
Author:  
DOI:  
10.29130/dubited.473988
Abstract:

In this study,N-substituted 5-nitrobenzimidazole ligands were reacted with [RuCl2(p-cymene)]2  and the corresponding complexes  were prepared and their structure were elucidated by elemental analysis, IR and NMR spectroscopic techniques. The synthesized Ru(II) complexes  were tested as catalysts for the transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence of KOH using 2–propanol as a hydrogen source at 82 ºC. This complexes was found to be an active catalyst in the catalytic transfer hydrogenation of ketones.

Keywords:

2019
Journal:  
Düzce Üniversitesi Bilim ve Teknoloji Dergisi
Author:  
DOI:  
10.29130/dubited.473988
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Düzce Üniversitesi Bilim ve Teknoloji Dergisi

Field :   Fen Bilimleri ve Matematik

Journal Type :   Ulusal

Metrics
Article : 1.636
Cite : 3.123
2023 Impact : 0.134
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Düzce Üniversitesi Bilim ve Teknoloji Dergisi