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Bu çalışmada piridin-2,6-dikarboksilik asitin (H2dipic), N-metilpiperazin (Meppz) ile reaksiyonundan proton transfer tuzu (H2Meppz)(Hdipic)2 (1) elde edilmiştir. Elde edilen proton transfer tuzunun (1) Ni(CH3COO)2.4H2O ve Cu(CH3COO)2.H2O ile reaksiyonundan ise metal kompleksleri [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O (2) ve (H2Meppz)[Cu(dipic)2].2H2O (3) sentezlenmiştir. Proton transfer tuzunun (1) yapısı FT-IR, 1H ve 13C NMR, ve UV-Vis spekroskopileri ve elementel analiz teknikleri ile aydınlatılmıştır. Komplekslerin yapıları ise FT-IR, UV-Vis, ICP-OES, manyetik duyarlılık ve elementel analiz yöntemlerinden elde edilen verilere göre önerilmiştir.
In this study, proton transfer salt (H2Meppz)(Hdipic)2 (1) was obtained from the reaction with pyridine-2,6-diarboxylic acid (H2dipic), N-methylpiperazine (Meppz). From the reaction of the proton transfer salt (1) Ni(CH3COO)2.4H2O and Cu(CH3COO)2.H2O the metal complexes [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O (2) and (H2Meppz)[Cu(dipic)2].2H2O (3) are synthesized. The structure of the proton transfer salt (1) is illuminated by FT-IR, 1H and 13C NMR, and UV-Vis specroscopies and elementary analysis techniques. The structures of the complexes are recommended based on the data obtained from FT-IR, UV-Vis, ICP-OES, magnetic sensitivity and elementary analysis methods.
Field : Fen Bilimleri ve Matematik; Mühendislik
Journal Type : Ulusal
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