Özet:

An analytical method for calculating the chemical potentials of the components of the gas-solid system based on thermodynamic calculations of carbon potentials of the С–О–Н–N gas mixture (combustion products of the methane-air mixture) and the solid phase (alloyed steel) is developed. Dependences describing the influence of the main parameters of heating the medium composition, flow rate, as well as their interaction, on metal losses associated with decarburization are obtained. Thermodynamic calculations of carbon potentials of alloyed steel and natural gas combustion products of different composition (α=0.2÷1.2), metal and combustion products temperatures of 1,100÷1,500 K are performed. Based on the analysis of the structure of the thermal and diffusion boundary layers, it is proved that the decrease in the temperature of the layer of combustion product flowing around the solid product and surface flow rate reduces the diffusion flow of carbon in the boundary layer. This effect reduces the decarburization of steel. It is found that when heating the heat unit according to the principle of indirect radiant heating (IRH) during the operation of the flat-flame burner, the main gas volume, localized at the metal surface, has a temperature significantly lower than the layer adjacent to the lining. This reduces the metal loss with decarburization compared with furnaces of the traditional heating system.Combustion of gas in flat-flame burners with an intense circulation of combustion products in the working space of the heat unit ensures that the heated products have a uniform composition of combustion products corresponding to a practically equilibrium one. This allows recommending flat-flame burners for widespread use in modern heat-power units in the industry Author Biographies Valeriy Nikolsky, Ukrainian State University of Chemical Technology Gagarin ave., 8, Dnipro, Ukraine, 49005 Doctor of Technical Sciences, Professor Department of Energetic

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