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  Citation Number 3
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Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi
2019
Journal:  
Selçuk Üniversitesi Fen Fakültesi Fen Dergisi
Author:  
Abstract:

Bu çalışmada çıkış maddesi olarak 5-aminoisoftalik asit (5-Aminobenzen-1,3-dikarboksilik asit) kullanıldı. 5-Aminobenzen-1,3-dikarboksilik asit ile ferrosenkarboksialdehitin kondenzasyon reaksiyonundan [[(3,5-dikarboksifenil)imino]karbonil]ferrosen elde edildi. Sonra literatürden faydalanılarak salisilaldehit ve etilendiamin ile kondenzasyon reaksiyonu ile dört dişli salen ligandı elde edildi. Daha sonra susuz FeCl3 ile kompleksi elde edildi ve sonuç ürün NH4OH ile dimerleştirilerek Schiff bazı içerikli ligand kompleksimiz olan [Fe(salen)2O] elde edildi. Daha önce sentezlediğimiz Schiff bazı ligand kompleksine [Fe(salen)2O] ligand kompleksini ilave ederek -COOH gruplarının kullanılması ile çift oksijen köprülü multinükleer kompleksler elde edildi. Sonuç olarak, elde edilen ligandların ve komplekslerin FT-IR, 1H NMR, elementel analizi ve manyetik süsseptibilite ölçümleri ile yapıları aydınlatıldı.

Keywords:

Schiff Synthesis of Some Ligand Complex Complex and Multinuclear Fe(III)/Fe(II)/Fe(III) Transitional Metal Complex
2019
Author:  
Abstract:

In this study, 5-aminoisoftalic acid (5-Aminobenzen-1,3-diarboxylic acid) was used as a output substance. 5-Aminobenzen-1,3-diarboxylic acid was obtained from the ferrosencarboxylaldehyde condensation reaction [(3,5-diarboxifenyl)iminocarbonyl]ferrosen. Then the literature was benefited with salicylaldehyde and etylendiamine with a condensation reaction and four-dental salin ligand was obtained. The complex was later obtained with the thirsty FeCl3 and the result was obtained [Fe(salen)2O], which is our ligand complex with some content by dimerizing the product with NH4OH. By adding the ligand complex [Fe(salen)2O] to some ligand complex we previously synthesized, the use of COOH groups achieved dual oxygen bridge multi-nuclear complexes. As a result, the structures of the obtained ligands and complexes were illuminated with FT-IR, 1H NMR, elementary analysis and magnetic decorability measurements.

Keywords:

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Selçuk Üniversitesi Fen Fakültesi Fen Dergisi

Field :   Fen Bilimleri ve Matematik; Ziraat, Orman ve Su Ürünleri

Journal Type :   Uluslararası

Metrics
Article : 308
Cite : 748
Selçuk Üniversitesi Fen Fakültesi Fen Dergisi