Abstract:

: This work developed a conductive ink composed of carbonaceous material for printing electrochemical sensors. The optimized ink comprises graphite, carbon black, and nail polish, respectively (35.3:11.7:53%), as well as acetone as a solvent. The proportion was optimized with consideration of the binder’s solubilization, the ink’s suitability for the screen-printing process, and lower electrical resistance. The materials used, and the resulting ink, were analyzed by way of Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), Raman spectroscopy, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The charge transfer resistance (Rct) obtained was 0.348 kΩ. The conductive ink was used to print an electrode on a PET substrate, and a flexible and disposable electrode was obtained. The electroactive area obtained was 13.7 cm 2, which was calculated by the Randles-Sevcik equation. The applicability of the device was demonstrated with a redox probe, providing a sensitivity of 0.02 µ A L mmol −1. The conductive ink has adequate homogeneity for producing electrodes using the screen-printing technique, with a low estimated production cost of $ 0.09 mL −1.

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