Özet:

The review of scientific development in the field of creation of new nanodimensional catalysts on the basis of complexes of metals with variable valency with carriers of the various nature is presented. Studied catalysts on the basis of the metals immobilized on carriers of the organic and inorganic nature, were tested in reaction of liquid phase oxidation of alkylaromatics and paraffin hydrocarbons by oxygen. The optimum parameters of carrying out processes were defined. The kinetics and thermodynamics of reactions of oxidation of hydrocarbons were studied. The mechanisms of activity of the catalytic systems were offered. Possibility of a reuse of catalysts in reactions of liquid phase oxidation of hydrocarbons has been shown shown. The selectivity of studied metal complex catalysts was defined.

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